Atomistry » Tungsten » Compounds » 9-Tungsto-arsenic Acid
Atomistry »
  Tungsten »
    Compounds »
      9-Tungsto-arsenic Acid »

9-Tungsto-arsenic Acid

9-Tungsto-arsenic Acid, luteo-arsenotungstic acid, may be obtained by saturation of a boiling solution of an alkali arsenate with tungstic anhydride, and allowing the mixture to stand for several weeks until the reactions of the 12-tungsto-arsenate have disappeared; or by acidifying a solution of one of its salts and shaking out with ether according to Drechsel. The acid is isomorphous with the corresponding phosphoric acid and has composition

H5[As(OH)(W2O7)4-W2O7-(W2O7)4(OH)As].36H2O.

It melts at 26° C. Only the ammonium and potassium salts of this series have been prepared. These are obtained by adding arsenic acid to a boiling solution of alkali tungstate until the colour becomes deep yellow, and then treating with ammonium or potassium chloride. On evaporation the solution yields lemon-yellow crystals of composition

R2O.As2O5.18WO3.14H2O (R = NH4, K).

Last articles

Zn in 9MJ5
Zn in 9HNW
Zn in 9G0L
Zn in 9FNE
Zn in 9DZN
Zn in 9E0I
Zn in 9D32
Zn in 9DAK
Zn in 8ZXC
Zn in 8ZUF
© Copyright 2008-2020 by atomistry.com
Home   |    Site Map   |    Copyright   |    Contact us   |    Privacy